Novel complex gel beads composed of hydrolyzed polyacrylamide and chitosan: An effective adsorbent for the removal of heavy metal from aqueous solution

A novel kind of complex gel beads containing HPAM (hydrolyzed polyacrylamide) and chitosan components (HPAM-chitosan gel beads) was prepared and applied in the removal of Cu2+, Pb2+, and Hg2+ ions from aqueous solutions. These gel beads exhibited a good performance for heavy metal removal. Moreover, the average diameter of these gel beads was about I mm, which could be appropriate for use in column, system. The removal order was Pb2+ > Cu2+ > Hg2+ under the same conditions. The effects of different experimental parameters, such as adsorbent dosage, initial pH, temperature, and initial metal concentration, on the adsorption capacities were studied. The Freundlich model gave a better fit to the experimental data than the Langmuir model in adsorption isotherm study. Desorption study indicated that the gel beads were easy to be regenerated. (C) 2009 Elsevier Ltd. All rights reserved.