Journal
BIORESOURCE TECHNOLOGY
Volume 100, Issue 17, Pages 3862-3868Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.biortech.2009.03.023
Keywords
Adsorption; Chitosan bead; Congo red; Surfactant
Funding
- Korea Science and Engineering Foundation (KOSEF)
- Advanced Environmental Biotechnology Research Center [R11-2003-006)]
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The adsorption performance of CS beads impregnated with triton X-100 (TX-100) as a nonionic surfactant and sodium dodecyl sulfate (SDS) as an anionic surfactant was investigated for the removal of anionic dye (congo red) from aqueous solution. While the adsorption capacity of CS/TX-100 beads was enhanced at all concentrations of TX-100 (0.005-0.1%), the increase in the concentration of SDS above 0.01% in the CS/SDS beads gradually reduced the adsorption capacity of the beads. Equilibrium adsorption isotherm data indicated a good fit to the Sips isotherm model and a heterogeneous adsorption process. The Sips maximum adsorption capacity in dry weight of the CS/TX-100 beads was 378.79 mg/g and 318.47 mg/g for the CS/SDS beads, higher than the 223.25 mg/g of the CS beads. Modification of CS beads by impregnation with nonionic surfactant, or even anionic surfactant, at low concentrations is a possible way to enhance adsorption of anionic dye. (C) 2009 Elsevier Ltd. All rights reserved.
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