4.8 Article

Functional 1,8-Naphthalimide AlE/AIEEgens: Recent Advances and Prospects

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 10, Issue 15, Pages 12081-12111

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.7b14473

Keywords

naphthalimide; aggregation-induced emission; nanoparticles; bio- and chemosensing; drug delivery; cell imaging OLEDs

Funding

  1. Department of Science and Technology (DST), New Delhi [DST/SERB/EMR/2014/000034, DST/TSG/PT/2009/23]
  2. DST-Max Planck Society, Germany [IGSTC/MPG/PG(PKI)/2011A/48]
  3. Department of Electronics & Information Technology, (Deity) [5(9)/2012-NANO (Vol. II)]

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This comprehensive review surveys the up-to-date development of aggregation-induced emission/aggregation-induced emission enhancement (AIE/AIEE) active naphthalimide (NI)-based smart materials with potential for wide and real world applications and that serves as a highly versatile building block with tunable absorption and emission in the complete visible region. The review article commences with a precise description of the importance of NI moiety and its several restricted area of applications owing to its aggregation caused quenching (ACQ) properties, followed by the discovery and importance of AlE/MEE-active Nis. The introduction section tracked an overview of the state of the art in NI luminogens in multiple applications. It also includes a few mechanistic studies on the structure property correlation of Nis and provides more insights into the condensed-state photophysical properties of small aggregation-prone systems. The review aims to ultimately accomplish current and forthcoming views comprising the use of the NIs for the detection of biologically active molecules, such as amino acids and proteins, recognition of toxic analytes, fabrication of light emitting diodes, and their potential in therapeutics and diagnostics.

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