Journal
RSC ADVANCES
Volume 8, Issue 67, Pages 38598-38605Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ra08241c
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Funding
- Hungarian Academy of Sciences
- Hungarian Science Foundation [OTKA PD124598]
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First representatives of a new family of isoquinolines, so called boroisoquinolines, were synthesized and characterized. The synthesis was based on the insertion of the difluoroboranyl group into the 1-methylidene-3,4-dihydroisoquinoline core. The optimization of the 2-difluoroboranyl-3,4-dihydroisoquinoline-1(2H)-ylidene core led to efficient fluorescence in a range of 400-600 nm with outstanding (>100 nm) Stokes shifts. The compounds might be suitable for reversible or irreversible labelling of proteins, particularly the cannabinoid receptor CB2.
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