Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 98, Pages 13845-13848Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc06496b
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Funding
- EU Marie Curie Initial Training Network FP7-PEOPLE-2012-ITN [316630 CAS-IDP]
- ERC [247450]
- EPSRC [EP/G006792, EP/F034210/1]
- Warwick Chancellor's Scholarship
- Warwick Spectroscopy RTP
- MRC [G0701062] Funding Source: UKRI
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l-Tryptophan (Trp), melatonin (MLT) and the Trp-peptide pentagastrin quenched the formation of azidyl radicals generated on irradiation of the anticancer complex trans,trans,trans-[Pt(pyridine)(2)(N-3)(2)(OH)(2)] with visible light, giving rise to C3-centred indole radicals which were characterized for Trp and MLT using an EPR spin-trap; indole, together with azidyl and hydroxyl radicals, have potential roles in a multitargeting mechanism of action against resistant cancers.
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