Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 98, Pages 13857-13860Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc06981f
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Funding
- project EXCILIGHT - European Union's Horizon 2020 Research and Innovation Programme [674990]
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The influence of phenyl linkage and donor strength on the photophysical properties of new derivatives of quinoxaline-containing iminodibenzyl and iminostilbene moieties is studied. The donor-acceptor derivatives showed dual thermally activated delayed fluorescence (TADF) and room temperature phosphorescence (RTP) despite a large energy gap between the excited singlet and triplet states (ca. 0.5 eV). This extremely rare observation is explained by the twisted and rigidified structure of the iminodibenzyl moiety.
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