Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 88, Pages 12467-12470Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc06564k
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Funding
- EPSRC [EP/M023346/1, EP/K03099X/1] Funding Source: UKRI
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The water/base intolerance of the previously reported electrophilic phosphonium cations has been overcome by replacing the labile electron-withdrawing groups generally attached to phosphorus (e.g. -F, -OAr, -CF3) with methyl groups. Tri-phosphorus(v) tricationic species, accessible in one-pot from commercially available materials, are air and water/base tolerant, yet are sufficiently Lewis acidic for catalysis.
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