Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 6, Issue 41, Pages 20402-20410Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ta06626d
Keywords
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Funding
- National Natural Science Foundation of China [U1401241, 51602354]
- Guangdong Natural Science Foundation of China [2015A030310462]
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Zinc-ion batteries (ZIBs) as an alternative to Li-ion batteries and lead-acid batteries possess many advantages, such as environmental friendliness, safety, and cost effectiveness. Many materials have been used as zinc-ion cathode materials. Yet, the critical technology about the relationship between a material's structure and the zinc storage performance is unclear and challenging. Herein, ultrathin (NH4)(2)V10O25 center dot 8H(2)O nanobelts were first demonstrated as a cathode material for ZIBs. The nanobelts have an interlayer spacing of 1.045 nm in the c-axis direction which is adjustable between 1.045 to 1.32 nm without structural damage during a facile Zn2+ insertion/extraction. The unique ultrathin and stable structure complemented by the large lamellar spacing enables a high Zn2+ diffusion. As a result, the (NH4)(2)V10O25 center dot 8H(2)O/Zn cell demonstrates a high rate capacity and a high specific energy of 225.4 W h kg(-1) and satisfactory cyclability (capacity retention of 90.1% after 5000 cycles). Our result provides a feasible and attractive solution for synthetic cathode materials for aqueous ZIBs.
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