Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 94, Pages 13228-13231Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc07671e
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Substitution of Ru(ii)-based chromophores with cheaper Cr(iii)-based complexes in optically active metallo-supramolecular architectures is limited by the lack of synthetic strategies leading to heteroleptic Cr(iii)-polypyridyl complexes with long excited-state lifetimes. Herein, we report on a versatile method yielding heteroleptic bis(terdentate) Cr(iii) complexes with room temperature millisecond range excited-state lifetimes, tuneable electronic and photophysical properties and easy anchoring possibilities.
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