Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 94, Pages 13256-13259Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc07060a
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Funding
- Natural Science and Engineering Research Council of Canada (NSERC) [RGPIN-06438]
- Canada Foundation for Innovation Leaders Opportunity Funds [227346]
- Canada Research Chair Program [CRC-227346]
- FRQNT Centre in Green Chemistry and Catalysis (CGCC) Strategic Cluster [RS-171310]
- Universite de Montreal
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The modular synthesis of a variety of trans 1,2-disubstituted cyclopropanes in a safe and user-friendly one-pot iron-catalyzed cyclopropanation reaction is described. Easily synthesized N-nosylhydrazones are used as diazo precursors, allowing the in situ generation of electron-rich diazo compounds under mild reaction conditions and their direct participation in the cyclopropanation reaction.
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