Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 94, Pages 13260-13263Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc07451h
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- Russian Science Foundation [18-13-00238]
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An unusual reactivity of nitrostyrenes in phosphorous acid was discovered, which permits the employment of these readily available synthons as 1,4-CCNO-dipole surrogates in a highly diastereoselective (4+1)-cycloaddition of indoles to afford 4H-spiro[indole-3,5-isoxazoles] in a diastereomerically pure form.
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