Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 95, Pages 13367-13370Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc07905f
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A regioselective oxidative C-H thio/selenocyanation of arenes and heteroarenes with TMSCN and elemental sulfur/selenium was demonstrated under catalyst-free and additive-free conditions. Dimethyl sulfoxide (DMSO) was employed as the mild oxidant as well as the solvent. The reaction is operationally simple and scalable with a broad substrate scope.
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