4.7 Article

Synergistic effect of bimetallic PdAu nanocrystals on oxidative alkyne homocoupling

Journal

CHEMICAL COMMUNICATIONS
Volume 54, Issue 93, Pages 13155-13158

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc06744a

Keywords

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Funding

  1. National Key R&D Program of China [2016YFA0202801, 2017YFA0700101]
  2. National Natural Science Foundation of China [21573119, 21590792, 21521091, 21390393, U1463202]
  3. China Postdoctoral Science Foundation [2018M631444]

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Bimetallic PdAu nanocrystals with different component ratios were obtained to investigate alkyne homocoupling. We found that the synergistic effect of Pd and Au plays an important role in the reaction. Alkynes with a variety of substituent groups could efficiently be converted into the corresponding 1,3-diynes through oxidative coupling.

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