Journal
ACS OMEGA
Volume 3, Issue 11, Pages 14575-14584Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsomega.8b01930
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Funding
- National Natural Science Foundation of China [21772001, 21702003]
- Natural Science Foundation of Anhui Province [1808085MB41, 1808085QB31]
- Start-up Research Fund of Anhui Normal University
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Efficient access to 8H-isoquinolino[1,2-b]quinazolin-8-ones and phthalazino[2,3-a]cinnoline-8,13-diones through cyclic amide-directed Ru(II)/Ir(III)-catalyzed C-H bond activation, has been developed. Consecutive C-H bond activation, carbene insertion, and condensation annulation processes were realized, affording 8H-isoquinolino[1,2-b]quinazolin-8-one and phthalazino[2,3-a]cinnoline-8,13-dione derivatives in good-to-excellent yields under mild conditions, with H2O and N-2 being generated as the only byproducts.
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