Facile Synthesis of an Organic Solid State Near-Infrared-Emitter with Large Stokes Shift via Excited-State Intramolecular Proton Transfer

An organic solid-state near-infrared (NIR)-emitter (lambda(em) = 738 nm) exhibiting large Stokes shift (Delta lambda = 293 nm) through the excited-state intramolecular proton transfer phenomenon has been synthesized and characterized. The present discovery points to the possibility of achieving a new family of solid-state NIR emitters starting from simple aldehyde and amine precursors.