Journal
CHEMICAL SCIENCE
Volume 9, Issue 43, Pages -Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8sc02981d
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- RSF [18-13-00196]
- Russian Science Foundation [18-13-00196] Funding Source: Russian Science Foundation
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The adduct free Lewis superacid Al(OCArF3)(3) was obtained by the reaction of ArF3COH with AlEt3 and fully characterized (Ar-F = C6F5). It comprises a high thermal stability up to 180 degrees C and a distinct reactivity towards Lewis bases, as exemplified by the isolation of the neutral adducts Al(OCArF3)D (D = MeCN, THF, Et2O, pyridine, OPEt3), the fluoride complexes [Q][FAl(OCArF)(3)] (Q(+) = Cs+, Ag+, Tl+, [S(NMe2)(3)](+), [Ph3C](+), Li+, [NBu4](+), [FeCp2](+)) and the chloride complex [Ph3C][ClAl(OCArF)(3)].
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