4.6 Article

Visible light-promoted difluoromethylthiolation of aryldiazonium salts

Journal

ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 16, Issue 44, Pages 8565-8568

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ob02431f

Keywords

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Funding

  1. Shandong Provincial Natural Science Foundation of China [ZR2016BQ31, ZR2016HM44, ZR2016JL009]
  2. Shandong Key Research Program of China [2017GSF218061]
  3. Major Program of Shandong Province Natural Science Foundation of China [ZR2017ZC0529]
  4. University of Jinan

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Difluoromethylthiolation of aryldiazonium salts under photocatalytic conditions with a shelf-stable, easily prepared and inexpensive reagent, PhSO2SCF2H was described. A variety of difluoromethylthioethers were obtained utilizing aryldiazonium salts containing different functional groups. Aryldiazonium salts with a heteroarene moiety were tolerated. Fluorescence quenching experiments indicated that both oxidative and reductive quenching cycles occurred during this process.

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