Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 16, Issue 44, Pages 8553-8558Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ob02338g
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Funding
- Thailand Research Fund [IRN58W0005, BRG6180005]
- Mahidol University
- Center of Excellence for Innovation in Chemistry (PERCH-CIC)
- Office of the Higher Education Commission (Franco-Thai Cooperation Program in Higher Education and Research, PHC Siam 2017)
- Institute for the Promotion of Teaching Science and Technology
- Science Achievement Scholarship of Thailand (SAST)
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Diverse 2-sulfonyl- and 2-thiocyanato-3-substituted quinolines were synthesized from o-alkynylisocyanobenzenes by nucleophilic addition of the respective sulfinate sodium salts and ammonium thiocyanate to the isocyanide moiety followed by cyclization. The salient features of the methodology include metal-free, ambient temperature and mild reaction conditions, ease of reagent handling, and broad functional group tolerance.
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