Journal
JOURNAL OF CHEMICAL PHYSICS
Volume 143, Issue 10, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.4929996
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Funding
- EPSRC [EP/I012303/1, L021366/1]
- University of Nottingham
- Engineering and Physical Sciences Research Council [EP/L021366/1, EP/I012303/1] Funding Source: researchfish
- EPSRC [EP/I012303/1, EP/L021366/1] Funding Source: UKRI
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We report vibrationally resolved spectra of the S-1 <- S-0 transition of chlorobenzene using resonance-enhanced multiphoton ionization spectroscopy. We study chlorobenzene-h(5) as well as its perdeuterated isotopologue, chlorobenzene-d5. Changes in the form of the vibrational modes between the isotopologues and also between the S-0 and S-1 electronic states are discussed for each species. Vibrational bands are assigned utilizing quantum chemical calculations, previous experimental results, and isotopic shifts, including those between the Cl-35 and Cl-37 isotopologues. Previous work and assignments of the S-1 spectra are discussed. Additionally, the vibrations in the ground state cation, D-0(+), are considered, since these have also been used by previous workers in assigning the excited neutral state spectra. (C) 2015 AIP Publishing LLC.
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