Journal
JOURNAL OF CHEMICAL PHYSICS
Volume 143, Issue 8, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.4928687
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Funding
- NSF [CNS-0619508]
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Rotational spectra of the weakly bound H2O-N2O complex and its HOD-N2O isotopologue in a supersonic jet are reported. Rotational constants of the singly substituted deuterium in water and each singly substituted nitrogen-15 are presented. Combinations of isotopic data and high level ab initio calculations place the water in a similar position to those of the isoelectronic H2O-CO2 complex, with a slight tilt of the OH towards the NNO axis. The deuterium nuclear quadrupole coupling constant places the deuterium on the O-H axis quasi-parallel to the NNO axis. (C) 2015 AIP Publishing LLC.
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