Journal
CHEMPHOTOCHEM
Volume 3, Issue 8, Pages 580-604Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cptc.201900097
Keywords
asymmetric synthesis; chirality; excited state proton transfer; fluorescence sensors; photoisomerization
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Excited state proton transfer (ESPT) is a unique photochemical process where the electron density shift of a molecule in the excited state dramatically decreases the pK(a) value of a proton donor site. A majority of ESPT research to date has focused on achiral molecules but there is growing interest in understanding/harnessing ESPT to/from chiral molecules. This review summarizes and critically examines the literature to date describing the role of ESPT in enantioselective fluorescence sensing, asymmetric synthetic organic chemistry, and photoisomerization of chiral molecules. Our goal is to show that despite ESPT of chiral molecules being a relatively new pursuit, there has been significant progress and even greater potential for ESPT in these and other applications yet to be realized.
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