4.2 Article

Density, Speed of Sound, Viscosity, and Excess Properties of Binary Mixtures Formed by Ethanol and Bis(trifluorosulfonyl)imide-Based Ionic Liquids

Journal

JOURNAL OF CHEMICAL AND ENGINEERING DATA
Volume 60, Issue 3, Pages 525-540

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/je500594z

Keywords

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Funding

  1. Ministerio de Ciencia y Tecnologia of Spain [CTQ2010-18848/PPQ]
  2. FEDER European Program
  3. Ministerio de Economia y Competitividad [BES-2011-04636]

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In this work, viscosities, densities, and speeds of sod of the binary mixtures containing the ionic liquids methylimidazolium bis(trifluoromethylsulfonyl)imide, [emim][NTf2], 1-butyl-3-methylimidazolium bis(trifltioromethylsulfonyl)imide, [bmim][NTf2], and 1-hexy1-3-methylimidazo-lium bis(trifluorornethylsulfonyl)imide, [hmim][NTf2], Mixed with ethanol were Measured at atmospheric pressure in the range of (278.15 to 338.15) K, covering the entire range of compositions. From these experimental data, the excess isentropic compressibility and molar isentropic compressibility Of pure components and mixtures have been calculated. Additionally, excess properties, such as viscosity deviation, excess molar volume, excess isentropic compressibility, and excess molar isentropic compressibility, have been calculated and fitted with the Redlich-Kister polynomial equation.

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