Journal
RSC ADVANCES
Volume 10, Issue 49, Pages 29373-29377Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0ra06554d
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Stereoselective and efficient synthesis of Gly-Gly-type (E)-methylalkene and (Z)-chloroalkene dipeptide isosteres is realized by organocuprate-mediated single electron transfer reduction. The synthetic isosteres can be used in Fmoc-based solid phase peptide synthesis, resulting in the preparation of the 14-mer RGG peptidomimetics containing an (E)-methylalkene or a (Z)-chloroalkene unit.
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