4.7 Article

Coordination polymers with a pyridyl-salen ligand for photocatalytic carbon dioxide reduction

Journal

CHEMICAL COMMUNICATIONS
Volume 56, Issue 29, Pages 4110-4113

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc00425a

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Funding

  1. National Basic Research Program of China [2017YFA0303504]
  2. National Natural Science Foundation of China [21573106]
  3. Priority Academic Program Development of Jiangsu Higher Education Institutions

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A new ligand H2L with pyridine and salen moieties and its coordination polymers (CPs) [Mn(L)Cl]center dot DMF (1) and [Fe(L)Cl]center dot DMF (2) were synthesized and their photocatalytic activity for the conversion of CO2 into CO under visible-light irradiation was investigated. This is the first instance of pyridyl-salen-ligand based CPs for photocatalyzing CO2 reduction.

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