Journal
CHEMICAL SOCIETY REVIEWS
Volume 50, Issue 3, Pages 1874-1912Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cs00254b
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Funding
- National Natural Science Foundation of China [22001117, 21971108, 21702098]
- Fundamental Research Funds for the Central Universities [020514380214]
- Natural Science Foundation of Jiangsu Province [BK20190006, BK20190285]
- China Postdoctoral Science Foundation [2020TQ0139]
- Foundation of Advanced Catalytic Engineering Research Center of the Ministry of Education [2020AC001]
- Innovation & Entrepreneurship Talents Plan of Jiangsu Province
- Jiangsu Six Peak Talent Project
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This article discusses the recent progress in organic synthesis of dinuclear gold-catalysis, highlighting the particular properties and advantages of dinuclear gold complexes. It summarizes the recent achievements of dinuclear gold-catalyzed coupling reactions, asymmetric catalysis, and photocatalysis.
Gold chemistry has developed extensively in the past decade, and a dozen good reviews have been presented discussing this progress. Few however have paid close attention to the progress in organic synthesis of dinuclear gold-catalysis. A dinuclear gold catalyst is defined here as a gold complex with two gold centers linked by a bidentate ligand. With theoretical analysis and some representative studies in recent years, this comprehensive review highlights the particular properties of dinuclear gold-complexes, especially aurophilic interactions, and systematically summarizes the recent achievements of dinuclear gold-catalyzed coupling reactions, asymmetric catalysis, and photocatalysis, where dinuclear gold catalysts tend to show a greater advantage than the mononuclear gold catalysts.
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