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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)
Copper(II)-catalyzed highly regio- and stereoselective hydrosilylation of unactivated internal alkynes with silylborate in water
Qing-Qing Xuan et al.
ORGANIC & BIOMOLECULAR CHEMISTRY (2015)
Anti-Selective Vicinal Silaboration and Diboration of Alkynoates through Phosphine Organocatalysis
Kazunori Nagao et al.
ORGANIC LETTERS (2015)
Temperature-Dependent Direct Enantioconvergent Silylation of a Racemic Cyclic Allylic Phosphate by Copper(I)-Catalyzed Allylic Substitution
Lukas B. Delvos et al.
SYNTHESIS-STUTTGART (2015)
Recent Advances in Transition-Metal-Catalyzed Silylations of Arenes with Hydrosilanes: C-X Bond Cleavage or C-H Bond Activation Synchronized with Si-H Bond Activation
Zheng Xu et al.
SYNTHESIS-STUTTGART (2015)
Boryl substitution of functionalized aryl-, heteroaryl- and alkenyl halides with silylborane and an alkoxy base: expanded scope and mechanistic studies
Eiji Yamamoto et al.
CHEMICAL SCIENCE (2015)
Site- and Regioselective Silaborative C-C Cleavage of 1-Alkyl-2-Methylenecyclopropanes Using a Platinum Catalyst with a Sterically Demanding Silylboronic Ester
Toshimichi Ohmura et al.
ACS CATALYSIS (2015)
Hydrosilylation reaction of olefins: recent advances and perspectives
Y. Nakajima et al.
RSC ADVANCES (2015)
Palladium-Catalyzed C-H Fluorosilylation of 2-Phenylpyridines: Synthesis of Silafluorene Equivalents
Qing Xiao et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)
Copper(II)-Catalyzed Silylation of Activated Alkynes in Water: Diastereodivergent Access to E- or Z-b-Silyl-α, β-Unsaturated Carbonyl and Carboxyl Compounds
Joseph A. Calderone et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)
Stereoselective Silylcupration of Conjugated Alkynes in Water at Room Temperature
Roscoe T. H. Linstadt et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)
Enantioselective Addition of Silicon Nucleophiles to Aldimines Using a Preformed NHC- Copper( I) Complex as the Catalyst
Alexander Hensel et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)
Silylative Cyclopropanation of Allyl Phosphates with Silylboronates
Ryo Shintani et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)
Copper(I)-Catalyzed Highly Regio- and Stereoselective Hydrosilylation of Terminal Alkynes with Boryldisiloxane
Hui Zhou et al.
CHEMCATCHEM (2014)
Synthesis of multi-substituted vinylsilanes via copper(I)-catalyzed hydrosilylation reactions of allenes and propiolate derivatives with silylboronates
Yun-He Xu et al.
CHEMICAL COMMUNICATIONS (2014)
Functional group directed C-H borylation
A. Ros et al.
CHEMICAL SOCIETY REVIEWS (2014)
Metal-catalyzed activation of ethers via C-O bond cleavage: a new strategy for molecular diversity
Josep Cornella et al.
CHEMICAL SOCIETY REVIEWS (2014)
CuI/Pd0 Cooperative Dual Catalysis: Tunable Stereoselective Construction of Tetra-Substituted Alkenes
Sebastien Vercruysse et al.
CHEMISTRY-A EUROPEAN JOURNAL (2014)
Cu(I)-NHC-Catalyzed Silylation of Allenes: Diastereoselective Three-Component Coupling with Aldehydes
James Rae et al.
CHEMISTRY-A EUROPEAN JOURNAL (2014)
Copper(I)-Catalyzed Regioselective Addition of Nucleophilic Silicon Across Terminal and Internal Carbon-Carbon Triple Bonds
Chinmoy K. Hazra et al.
CHEMISTRY-AN ASIAN JOURNAL (2014)
Selective Synthesis of Multisubstituted Olefins Utilizing gem- and vic-Diborylated Vinylsilanes Prepared by Silylborylation of an Alkynylboronate and Diborylation of Alkynylsilanes
Jiao Jiao et al.
JOURNAL OF ORGANIC CHEMISTRY (2014)
Syntheses of 2-silicon-substituted 1,3-dienes
Partha P. Choudhury et al.
JOURNAL OF ORGANOMETALLIC CHEMISTRY (2014)
Construction of Homoallylic Alcohols from Terminal Alkynes and Aldehydes with Installation of syn-Stereochemistry
Tomoya Miura et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)
A Mild Ni/Cu-Catalyzed Silylation via C-O Cleavage
Cayetana Zarate et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)
Copper-Catalyzed Regiodivergent Silacarboxylation of Allenes with Carbon Dioxide and a Silylborane
Yosuke Tani et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)
Cu(I)-NHC Catalyzed Asymmetric Silyl Transfer to Unsaturated Lactams and Amides
Vittorio Pace et al.
ORGANIC LETTERS (2014)
Formal Carbon Insertion of N-Tosylhydrazone into B-B and B-Si Bonds: gem-Diborylation and gem-Silylborylation of sp3 Carbon
Huan Li et al.
ORGANIC LETTERS (2014)
Nanogold-Catalyzed cis-Silaboration of Alkynes with Abnormal Regioselectivity
Charis Gryparis et al.
ORGANIC LETTERS (2014)
Catalytic Enantioselective Silylation of N-Sulfonylimines: Asymmetric Synthesis of α-Amino Acids from CO2 via Stereospecific Carboxylation of α-Amino Si lanes
Tsuyoshi Mita et al.
ORGANIC LETTERS (2014)
CuI-Catalyzed Conjugate Addition of Silyl Boronic Esters: Retracing Catalytic Cycles Using Isolated Copper and Boron Enolate Intermediates
Jacqueline Plotzitzka et al.
ORGANOMETALLICS (2014)
McQuade's Six-Membered NHC-Copper(I) Complexes for Catalytic Asymmetric Silyl Transfer
Lukas B. Delvos et al.
SYNTHESIS-STUTTGART (2014)
Formal Nucleophilic Boryl Substitution of Organic Halides with Silylborane/Alkoxy Base System
Eiji Yamamoto et al.
TOPICS IN CATALYSIS (2014)
Enantioselective Syntheses of α-Silyl Amines via a Copper-N-Heterocyclic Carbene Catalyzed Nucleophilic Silicon Transfer to Imines
Chunliang Zhao et al.
ASIAN JOURNAL OF ORGANIC CHEMISTRY (2014)
Regio- and Stereoselective Synthesis of Tri- and Tetrasubstituted Enamides via Palladium-Catalyzed Silaboration of Ynamides
Nozomi Saito et al.
ADVANCED SYNTHESIS & CATALYSIS (2013)
Synthesis of Acylsilanes by Copper(I)-Catalyzed Addition of Silicon Nucleophiles onto Acid Derivatives
Virginie Cirriez et al.
ADVANCED SYNTHESIS & CATALYSIS (2013)
Asymmetric Synthesis of -Chiral Allylic Silanes by Enantioconvergent -Selective Copper(I)-Catalyzed Allylic Silylation
Lukas B. Delvos et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)
Copper-Catalyzed Addition of Nucleophilic Silicon to Aldehydes
Virginie Cirriez et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)
NHC-Cu(I) catalysed asymmetric conjugate silyl transfer to unsaturated lactones: application in kinetic resolution
Vittorio Pace et al.
CHEMICAL COMMUNICATIONS (2013)
Activation of the Si-B Interelement Bond: Mechanism, Catalysis, and Synthesis
Martin Oestreich et al.
CHEMICAL REVIEWS (2013)
Exceptionally E- and β-Selective NHCCu-Catalyzed Proto-Silyl Additions to Terminal Alkynes and Site- and Enantioselective Proto-Boryl Additions to the Resulting Vinylsilanes: Synthesis of Enantiomerically Enriched Vicinal and Geminal Borosilanes
Fanke Meng et al.
CHEMISTRY-A EUROPEAN JOURNAL (2013)
On the structural diversity of [K(18-crown-6)EPh3] complexes (E = C, Si, Ge, Sn, Pb): synthesis, crystal structures and NOESY NMR study
Christian Kleeberg
DALTON TRANSACTIONS (2013)
On the Reactivity of Silylboranes toward Lewis Bases: Heterolytic BSi Cleavage vs. Adduct Formation
Christian Kleeberg et al.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2013)
Regio- and Diastereoselective Copper(I)-Catalyzed Allylic Substitution of δ-Hydroxy Allylic Chlorides by a Silicon Nucleophile
Chinmoy K. Hazra et al.
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2013)
Cu(II)-Catalyzed Allylic Silylation of Morita-Baylis-Hillman Alcohols via Dual Activation of Si-B Bond and Hydroxyl Group
Qing-Qing Xuan et al.
JOURNAL OF ORGANIC CHEMISTRY (2013)
Enantioselective Synthesis of α-Tri- and α-Tetrasubstituted Allylsilanes by Copper-Catalyzed Asymmetric Allylic Substitution of Allyl Phosphates with Silylboronates
Momotaro Takeda et al.
JOURNAL OF ORGANIC CHEMISTRY (2013)
One-Pot Synthesis of α-Amino Acids from CO2 Using Bismetal Reagents
Tsuyoshi Mita et al.
JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN (2013)
Synthesis of Multisubstituted Olefins through Regio- and Stereoselective Silylborylation of an Alkynylboronate/Chemoselective Cross-Coupling Sequences
Jiao Jiao et al.
ORGANIC LETTERS (2013)
Iterative Asymmetric Allylic Substitutions: syn- and anti-1,2-Diols through Catalyst Control
Jin Kyoon Park et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)
Copper-Catalyzed Silacarboxylation of Internal Alkynes by Employing Carbon Dioxide and Silylboranes
Tetsuaki Fujihara et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)
Unprecedented Copper(I) Bifluoride Complexes: Synthesis, Characterization and Reactivity
Thomas Vergote et al.
CHEMISTRY-A EUROPEAN JOURNAL (2012)
Catalytic Functionalization of Methyl Group on Silicon: Iridium-Catalyzed C(sp3)-H Borylation of Methylchlorosilanes
Toshimichi Ohmura et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)
Tunable Cross Coupling of Silanols: Selective Synthesis of Heavily Substituted Allenes and Butadienes
Hui Zhou et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)
Enhanced Catalyst Activity and Enantioselectivity with Chirality-Switchable Polymer Ligand PQXphos in Pd-Catalyzed Asymmetric Silaborative Cleavage of meso-Methylenecyclopropanes
Yuto Akai et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)
Anomalous Reactivity of Silylborane: Transition-Metal-Free Boryl Substitution of Aryl, Alkenyl, and Alkyl Halides with Silylborane/Alkoxy Base Systems
Eiji Yamamoto et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)
One-Pot Synthesis of α-Amino Acids from CO2 Using a Bismetal Reagent with Si-B Bond
Tsuyoshi Mita et al.
ORGANIC LETTERS (2012)
NHC-Cu-Catalyzed Silyl Conjugate Additions to Acyclic and Cyclic Dienones and Dienoates. Efficient Site-, Diastereo- and Enantioselective Synthesis of Carbonyl-Containing Allylsilanes
Kang-sang Lee et al.
ORGANOMETALLICS (2012)
tert-Butoxide-Assisted Amidation of Esters under Green Conditions
Bo Ram Kim et al.
SYNTHESIS-STUTTGART (2012)
Nickel-Catalyzed Cross-Couplings Involving Carbon-Oxygen Bonds
Brad M. Rosen et al.
CHEMICAL REVIEWS (2011)
Regioselectivity of the borylation of alkanes and arenes
John F. Hartwig
CHEMICAL SOCIETY REVIEWS (2011)
Copper-Catalyzed 1,2-Addition of Nucleophilic Silicon to Aldehydes: Mechanistic Insight and Catalytic Systems
Christian Kleeberg et al.
CHEMISTRY-A EUROPEAN JOURNAL (2011)
Recent advances and actual challenges in late transition metal catalyzed hydrosilylation of olefins from an industrial point of view
Dennis Troegel et al.
COORDINATION CHEMISTRY REVIEWS (2011)
Metal-Free Catalytic C-Si Bond Formation in an Aqueous Medium. Enantioselective NHC-Catalyzed Silyl Conjugate Additions to Cyclic and Acyclic α,β-Unsaturated Carbonyls
Jeannette M. O'Brien et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)
Stereoconvergent Synthesis of Chiral Allylboronates from an E/Z Mixture of Allylic Aryl Ethers Using a 6-NHC-Cu(I) Catalyst
Jin Kyoon Park et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)
Exploration of New C-O Electrophiles in Cross-Coupling Reactions
Da-Gang Yu et al.
ACCOUNTS OF CHEMICAL RESEARCH (2010)
Copper-Catalyzed Si-B Bond Activation in Branched-Selective Allylic Substitution of Linear Allylic Chlorides
Devendra J. Vyas et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2010)
C-H Activation for the Construction of C-B Bonds
Ibraheem A. I. Mkhalid et al.
CHEMICAL REVIEWS (2010)
Enantioselective Conjugate Silyl Additions to Cyclic and Acyclic Unsaturated Carbonyls Catalyzed by Cu Complexes of Chiral N-Heterocyclic Carbenes
Kang-sang Lee et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)
Switch of Regioselectivity in Palladium-Catalyzed Silaboration of Terminal Alkynes by Ligand-Dependent Control of Reductive Elimination
Toshimichi Ohmura et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)
A Chiral 6-Membered N-Heterocyclic Carbene Copper(I) Complex That Induces High Stereoselectivity
Jin Kyoon Park et al.
ORGANIC LETTERS (2010)
Silylboranes as New Tools in Organic Synthesis
Toshimichi Ohmura et al.
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN (2009)
Silylboranes bearing dialkylamino groups on silicon as silylene equivalents: Palladium-catalyzed regioselective synthesis of 2,4-disubstituted siloles
Toshimichi Ohmura et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2008)
Iridium-Catalyzed Preparation of Silylboranes by Silane Borylation and Their Use in the Catalytic Borylation of Arenes
Timothy A. Boebel et al.
ORGANOMETALLICS (2008)
Palladium-catalyzed asymmetric silaborative C-C cleavage of meso-methylenecyclopropanes
Toshimichi Ohmura et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2007)
Synthesis of silylboronic esters functionalized on silicon
Toshimichi Ohmura et al.
ORGANOMETALLICS (2007)
Stereoselective synthesis of chiral 3-aryl-1-alkynes from bromoallenes and heterocuprates
AM Caporusso et al.
JOURNAL OF ORGANIC CHEMISTRY (2006)
Element-element additions to unsaturated carbon-carbon bonds catalyzed by transition metal complexes
Irina Beletskaya et al.
CHEMICAL REVIEWS (2006)
Stereoselective synthesis of (Z)-1-silyl-2-stannylethene by palladium-catalyzed silastannation of ethyne and its synthetic transformations
M Murakami et al.
SYNTHESIS-STUTTGART (2004)
Regio- and stereoselective synthesis of boryl-substituted allylsilanes via transition metal-catalyzed silaboration
M Suginome et al.
JOURNAL OF ORGANOMETALLIC CHEMISTRY (2003)
Chemistry of boron, part 250 -: 2-Triorgano-silyl, -germyl, -stannyl and -plumbyl derivatives of 1,3-diisopropyl-benzo-1,3,2-diazaborolidine and related compounds and their reactions with (η2-C2H4)Pt(PPh3)2
T Habereder et al.
APPLIED ORGANOMETALLIC CHEMISTRY (2003)
Highly regio- and stereoselective silylstannation of allenes catalyzed by phosphine-free palladium complexes
M Jeganmohan et al.
CHEMICAL COMMUNICATIONS (2002)
Silylstannation of terminal alkynes using a recyclable palladium(0) catalyst immobilised in an ionic liquid
I Hemeon et al.
CHEMICAL COMMUNICATIONS (2002)
Regio- and stereochemical control in bis-functionalization-cyclization: Use of alleneyne precursors for carbocyclic and heterocyclic synthesis
S Shin et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2001)
Palladium- and platinum-catalyzed silaboration of methylenecyclopropanes through selective proximal or distal C-C bond cleavage
M Suginome et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2000)
Convenient preparation of silylboranes
M Suginome et al.
ORGANOMETALLICS (2000)
Transition-metal-catalyzed additions of silicon-silicon and silicon-heteroatom bonds to unsaturated organic molecules
M Suginome et al.
CHEMICAL REVIEWS (2000)
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