Journal
DALTON TRANSACTIONS
Volume 50, Issue 3, Pages 1119-1125Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0dt03536j
Keywords
-
Categories
Funding
- National Natural Science Foundation of China [21301174, 21861005]
- Shandong Provincial Natural Science Foundation [ZR2018LB006]
- Youth Innovation Team of Shandong Colleges and Universities [2019KJC027]
- Liaocheng University [318051722]
Ask authors/readers for more resources
Two complexes were successfully synthesized by varying the hydrazone ligands in the Dy-phosphonate system, resulting in significant structural transformations. Magnetic studies indicated similar single molecule magnet behaviors for both complexes, demonstrating an effective molecular assembly tactic for developing highly complicated lanthanide coordination clusters.
{Dy-16(mu(6)-C10H7PO3)(2)(mu(5)-C10H7PO3)(8)(spch)(8)(mu(3)-OH)(2)(mu(2)-OH)(2)(mu(2)-AcO)(6)(mu(3)-COO)(2)(DMF)(2)(H2O)(6)}center dot 0.5CH(3)OH center dot 4.5H(2)O (1) and {Dy-16(mu(5)-C10H7PO3)(4)(mu(3)-C10H7PO3)(12)(mu(2)-C10H7PO3H)(8)(opch)(4)(DMF)(8)(MeOH)(4)}center dot 2.5CH(3)OH center dot 3H(2)O (2), where H(2)spch is ((E)-N '-(2-hydroxybenzylidene)pyrazine-2-carbohydrazide, C10H7PO3H2 is 1-naphthylphosphonic acid and H(2)opch is (E)-N '-(2-hydroxy-3-methoxybenzylidene)pyrazine-2-carbohydrazide, were successfully synthesized by varying the hydrazone ligands in the Dy-phosphonate system. It is important that the ellipsoidal core experiences a ring forming structural transformation to the supramolecular square motif upon the incorporation of an ortho-methoxy substituent into the hydrazone. Alternating-current (ac) magnetic susceptibility studies of 1 and 2 suggest that similar single molecule magnet behaviors occur for these two complexes. The result represents an effective molecular assembly tactic to develop highly complicated lanthanide coordination clusters through the multicomponent self-assembly of the coalescence of phosphonate- and hydrazone-based ligands and metal salts.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available