Journal
APPLIED CATALYSIS B-ENVIRONMENTAL
Volume 317, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.apcatb.2022.121689
Keywords
Biomass conversion; Copper catalyst; LaOx; Diols; Lactone
Funding
- National Natural Science Foundation of China [21872134, 22072142]
- Fundamental Research Fund for the Central Universities [2412022QD020, 2412021YJ003]
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This study reveals the outstanding catalytic performance of CuLa0.25/Al2O3 catalyst in the hydrogenation of lactones to diols, with LaOx playing a crucial role in promoting catalyst selectivity and stability.
The activation and ring opening reaction of lactone bond is of great significance in biomass utilization. Cu-based catalysts are widely used in the biomass hydrogenation processes, in which the effect of oxide promoters on Cu catalysts is one of the most attractive research topics. Herein, the transformation of lactones to diols over Cu/Al2O3 and CuLax/Al2O3 catalysts was studied and the promoting role of LaOx has been discussed. The CuLa0.25/Al2O3 catalyst showed outstanding catalytic performance with high 1,4-butanediol yield of > 90 %, and it also showed high efficiency for the hydrogenation of series of five- and six-membered lactones (gamma-butyrolactone, gamma-valerolactone, delta-hexalactone, etc) to diols. Based on the comprehensive analysis of the XRD, TEM, TPR, XPS, low temperature CO-DRIFT results, the crucial contribution of LaOx species in promoting the selectivity and stability of catalysts were investigated in detail. The presence of LaOx species not only results in the formation of Cu+-LaOx interfacial active sites, which facilitate the adsorption and activation of lactones, but also promotes the stability of catalyst.
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