Journal
ORGANIC CHEMISTRY FRONTIERS
Volume -, Issue -, Pages -Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2qo01118b
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Funding
- National Natural Science Foundation of China [21976112, 21927811, 52102008]
- Local Science and Technology Development Fund Guided by the Central Government [YDZX20203700002586]
- National Key R&D Program of China [2019YFA0210100]
- Natural Science Foundation of Shandong Province of China [ZR2021MB031, ZR2020JQ10]
- Major Science and Technology Innovation Project of Shandong Province [2021ZDSYS09]
- China Postdoctoral Science Foundation [2020M682204]
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A tandem 2-azidoallylation/click cycloaddition reaction has been demonstrated to efficiently construct novel multifunctional hepta-1,6-dienes with quaternary/tertiary carbon centers and a bis-1,2,3-triazole scaffold.
A tandem 2-azidoallylation/click cycloaddition reaction can be accomplished with methylene compounds, phenolic substituted vinyl azide and alkynes in one pot. This general cascade reaction smoothly enables the construction of novel multifunctional hepta-1,6-dienes bearing quaternary/tertiary carbon and a bis-1,2,3-triazole scaffold in good to excellent yields.
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