4.7 Article

Facile fabrication of antibacterial and fire-safety multifunctional cotton fabric with a triazine-phosphonate N-halamine

Journal

INDUSTRIAL CROPS AND PRODUCTS
Volume 186, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.indcrop.2022.115261

Keywords

Cotton; Antibacterial; Flame retardant; N-halamine; Phosphonate

Funding

  1. National Natural Science Foundation of China [51703101]
  2. Natural Science Foundation of Shandong Province [RZ2100001481]

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The research aims to develop a multi-purpose cotton fabric with biocidal efficacy and flame retardancy. The modified cotton fabric showed strong bactericidal effect against both positive and negative bacteria within 1 minute, and successfully passed the flame test with self-extinguishing effect. Additionally, the multi-purpose coating had slight influence on the performance of cotton fabric.
Cotton fabric, a cellulose-based substance, is widely utilized in our daily lives, yet it is simple to breed micro-organisms and cause fires, a problem that must be addressed immediately. The goal of this research was to create a multi-purpose cotton fabric with biocidal efficacy and flame retardacy to lift a hand against harmful micro-organism and fire hazard. To achieve this target, the typical reactivity of cyanuric chloride was utilized, and a reactive triazine-phosphonate N-halamine precursor (TDAD) was designed and deposited onto cotton fabric through traditional method. After chlorination, TDAD-modified cotton fabric presented strongly bactericidal effect against both positive and negative bacteria, all of which could be inactivated within 1 min. In addition, the multi-purpose cotton fabric demonstrated satisfactory flame retardancy with 27.5 % of LOI value and success-fully passed the flame test with self-extinguishing effect due to the joint effect of P and N elements. Furthermore, the multi-purpose coating displayed slight influence on the cytocompatibility, tensile strength and whiteness of cotton fabric. Consequently, this work offers an efficient mean to prepare multi-purpose cotton fabric with high performance.

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