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CHEMICAL PHYSICS LETTERS
Volume 316, Issue 1-2, Pages 60-66Publisher
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DOI: 10.1016/S0009-2614(99)01263-4
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The rotationally resolved, resonant photodissociation spectrum of CoO+ has been obtained for the first time. Transitions from the ground state to two excited electronic states are observed, (5)Phi(5) - (5)Delta(4) and (5)Pi(3), - (5)Delta(4) with electronic origins (T-00) at 16713 +/- 10 cm(-1) and 17588 +/- 10 cm(-1), respectively. The zero point rotational constant of the (5)Delta(4) ground state of CoO+ is found to be B-0 = 0.492 +/- 0.006 cm(-1), resulting in an experimental bond length of r(0) = 1.65 +/- 10.01 Angstrom. The excited states have longer bond lengths (r(0)' = 1.86 +/- 0.01 Angstrom) consistent with the charge transfer nature of the transition. These results are compared with ab initio predictions. (C) 2000 Elsevier Science B.V. All rights reserved.
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