4.4 Article

The synthesis and functionalisation of quinuclidine enamine N-oxide and borane complex

Journal

TETRAHEDRON LETTERS
Volume 41, Issue 2, Pages 271-274

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(99)02033-X

Keywords

carbanions; N-oxides; enamines; boron; boron compounds

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The synthesis of quinuclidine enamine N-oxide and quinuclidine enamine borane complex is described. Selective deprotonation of the double bond allows the direct functionalisation at the alpha-position with a range of electrophiles. (C) 1999 Elsevier Science Ltd. All rights reserved.

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