Journal
JOURNAL OF CHEMICAL PHYSICS
Volume 112, Issue 2, Pages 509-512Publisher
AMER INST PHYSICS
DOI: 10.1063/1.480541
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Dynamical heterogeneity and the decoupling of diffusion and relaxation in a supercooled liquid is investigated via a time-dependent, four-point density correlation function. We show that the main contribution to the corresponding generalized susceptibility chi(4)(t) in a molecular dynamics simulation of a Lennard-Jones liquid arises from spatial correlations between temporarily localized (caged) particles. By comparing chi(4)(t) with a generalized susceptibility chi(M)(t) related to a correlation function for the squared particle displacements, we demonstrate a connection between dynamical heterogeneity and the decoupling of relaxation and diffusion. (C) 2000 American Institute of Physics. [S0021-9606(00)52402-7].
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