Journal
THERMOCHIMICA ACTA
Volume 343, Issue 1-2, Pages 49-56Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/S0040-6031(99)00379-2
Keywords
isotherms; moisture content; persimmon; thermodynamic properties
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Moisture equilibrium data of persimmon skin and pulp were determined using the static gravimetric method. Adsorption and desorption isotherms were obtained in the range of 20-70 degrees C, to water activities (a(w)) from 0.02 to 0.85. The application of the GAB model to the experimental results, using direct nonlinear regression analysis, provided a good agreement between experimental and calculated values. The net isosteric heat of sorption was estimated from equilibrium sorption data, using the Clausius-Clapeyron equation. Isosteric heats of sorption were found to increase with increasing temperature and could be well adjusted by an exponential relationship. The enthalpy-entropy compensation theory was applied to sorption isotherms and plots of Delta H versus Delta S for skin and pulp provided the isokinetic temperatures, indicating an enthalpy controlled sorption process. (C) 2000 Elsevier Science B.V. All rights reserved.
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