Journal
ORGANIC LETTERS
Volume 2, Issue 2, Pages 159-161Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol991260s
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[GRAPHICS] Ytterbium trifluoromethanesulfonate [Yb(OTf)(3)] catalyzed the imino ene reaction of N-tosyl aldimine with alpha-methylstyrene to give a homoallylamine in moderate yield. Furthermore, addition of a catalytic amount of chlorotrimethylsilane (TMSCI) dramatically enhanced the imino ene reaction.
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