Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 65, Issue 2, Pages 295-296Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo990771p
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A new polymer-supported BINOL (1,1'-Bi-2-naphthol) :was synthesized by coupling of aminomethyl polystyrene resin and (S)-2,2'-dihydroxy-1,1'-binaphthyl-3,3'-dicarboxylic acid. This new ligand was found to be more enantioselective for the asymmetric addition of diethylzinc to aldehydes than its free analog [Ti(BINOL)(PrO2)-Pr-i]. A range of 57-99% ee's as well as 78-97% yields was obtained, and: the electronic properties of the enantioselectivity were also observed.
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