Journal
METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE
Volume 31, Issue 1, Pages 35-41Publisher
SPRINGER
DOI: 10.1007/s11663-000-0128-6
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Reduction of celestite (SrSO4) powder with particles of active charcoal has been studied extensively in the absence and presence of catalysts. The optimum temperature at the charging zone has been optimized to get a maximum water-soluble strontium sulfide value. The strontium value has been analyzed using a chemical method, which was verified by the instrumental method using an inductively coupled plasma-optical emission spectrophotometer (ICP-OES). The conversion-time data have been analyzed by using a modified volume-reaction (MVR) model, and the effect of the catalyst on kinetic parameters has been elucidated. It was found that potassium carbonate, potassium dichromate, sodium carbonate, and sodium dichromate catalysts were found to enhance the reaction rate quite satisfactorily in the reduction of the celestite (SrSO4).
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