4.7 Article

Iron versus ruthenium oxidation in 1,1′-bis(diphenylphosphino)ferrocene-ruthenium(II) complexes:: EPR and spectroelectrochemical evidence

Journal

INORGANIC CHEMISTRY COMMUNICATIONS
Volume 3, Issue 2, Pages 80-82

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/S1387-7003(00)00009-5

Keywords

EPR; ferrocene compounds; oxidation; ruthenium complexes; spectroelectrochemistry

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Oxidation of [Cp*RuH(dppf)] (1), dppf = 1,1'-bis(diphenylphosphino)ferrocene, and [(Cym)RuCl(dppf)](PF6) (2), Cym = p-cymene, occurs at ruthenium for 1 but yields a ferrocenium species for compound 2. (C) 2000 Elsevier Science S.A. All rights reserved.

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