Journal
THIN SOLID FILMS
Volume 360, Issue 1-2, Pages 213-221Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/S0040-6090(99)00871-8
Keywords
nonlinear optical properties; sol-gel; chalcone
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We report the syntheses of two triethoxysilanes for thin film fabrication. One silane (SGDR1) contains disperse red 1 (DR1) which is a second-order nonlinear optical (NLO) active chromophore. The other silane (SGCHC) bears a chalcone derivative. In order to improve the poor temporal stability of second-order NLO effects in the resulting poled sol-gel film, photo-crosslink was induced between the double bonds in chalcone units after mixing SGDR1 and SGCHC. Under UV exposure, the photocrosslink was studied with W-visible absorption and IR vibrational spectroscopy. The decaying behavior of the molecular order parameter (A(2)) after corona poling was investigated using polarized absorption spectroscopy (PAS). Second-order non-linear optical properties of the sample were studied using second-harmonic generation (SHG) and linear electro-optic (E/O) signal measurement. Poled and UV-cured film of SGDR1/SGCHC exhibited much better stability than thermally poled sample with respect to the molecular order parameter and linear electro-optic effect. (C) 2000 Elsevier Science S.A. All rights reserved.
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