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Regioselective reduction of 4,6-O-benzylidenes using triethylsilane and BF3•Et2O

Journal

TETRAHEDRON-ASYMMETRY
Volume 11, Issue 2, Pages 385-387

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0957-4166(99)00584-4

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The 4,6-di-O-benzylidene acetals of glucose, mannose, glucosamine, and galactose were regioselectively reduced by triethylsilane in the presence of BF3. Et2O to yield the 6-O-benzyl ethers in good to excellent yields. (C) 2000 Elsevier Science Ltd. All rights reserved.

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