4.4 Article

Direct detection of intramolecular Sb•••N nonbonded interaction by 1H-13C and 1H-15N heteronuclear multiple bond correlation spectroscopy

Journal

TETRAHEDRON LETTERS
Volume 41, Issue 7, Pages 1031-1034

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(99)02189-9

Keywords

intramolecular nonbonded interaction; H-1-C-13 HMBC; H-1-N-15 HMBC; J-HMBC 2D

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Direct evidence of intramolecular Sb ... N nonbonded interaction was obtained by means of H-1-C-13 and H-1-N-15 heteronuclear multiple bond correlation (HMBC) experiments. The long-range coupling constants between H-1 and C-13 nuclei through antimony and nitrogen were also determined by the J-HMBC 2D method. (C) 2000 Elsevier Science Ltd. All rights reserved.

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