Polarized Raman study of aligned multiwalled carbon nanotubes

Polarized Raman spectra of high purity aligned arrays of multiwalled carbon nanotubes, prepared on silica substrates from the thermal decomposition of a ferrocene-xylene mixture, show a strong dependence of the graphitelike G band and the disorder-induced D band on the polarization geometry employed in the experiments. The experimental G-band intensity exhibits a minimum at theta(m) = 55 degrees in the VV configuration, in good agreement with theoretical predictions of a characteristic minimum at 54.7 degrees for A(1g) modes in single wall nanotubes, where theta(m) denotes the angle between the polarization direction and the nanotube axis.