Journal
CHEMICAL PHYSICS LETTERS
Volume 318, Issue 4-5, Pages 466-470Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/S0009-2614(00)00044-0
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The photofragment spectra of jet-cooled and rotationally thermalized AuCH2+ are reported. Two channels are observed: loss of H-2 and loss of CH2 with a branching ratio of 1.4:1 over the region studied. The presence of a threshold at 322 nm for the dissociation of jet-cooled AuCH2+ to Au+ + CH2 implies the upper limit D(0)degrees(Au+-CH2) less than or equal to 372 +/- 3 kJ mol(-1). The dissociation threshold of ions rotationally thermalized in an ion trap shifts to lower energy by the amount of parent rotational energy. (C) 2000 Elsevier Science B.V. All rights reserved.
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