Journal
TETRAHEDRON LETTERS
Volume 41, Issue 10, Pages 1619-1622Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(99)02343-6
Keywords
allenes; cyclization; nitrogen heterocycles; palladium catalysis
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A series of allenic tosylamides have been prepared and shown to undergo palladium(II)-catalyzed cyclization in the presence of lithium bromide and a copper(II) salt to give pyrrolidines. Palladium-catalyzed 1,2-oxidation of allenic lactams in the presence of LiBr and p-benzoquinone was also studied. (C) 2000 Elsevier Science Ltd. All rights reserved.
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