Journal
ORGANIC LETTERS
Volume 2, Issue 5, Pages 713-715Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol005583w
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- NIGMS NIH HHS [GM 46059] Funding Source: Medline
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[GRAPHICS] The asymmetric reduction of N-aryl imines to yield chiral amines with enantiomeric excesses above 90% was achieved. Ethylenebis(eta(5)-tetrahydroindenyl)titanium difluoride ((EBTHI)TiF2, 1) was employed as the precatalyst with polymethylhydrosiloxane (PMHS) as the stoichiometric reducing agent. A variety of N-aryl imines derived from nonaromatic ketones were reduced with high ee.
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