Journal
APPLIED CATALYSIS A-GENERAL
Volume 194, Issue -, Pages 475-477Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/S0926-860X(99)00393-2
Keywords
sulfide; imidation; sulfimidation; sulfimide; (salen)manganese(III) complex
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Enantioselective sulfimidation of alkyl phenyl sulfides was achieved by using (R,R)-Mn-salen complex 5 as a catalyst. In the sulfimidation of methyl and benzyl phenyl sulfides, high enantioselectivity (up to 89% ee) was attained in the presence of N-methylmorpholine N-oxide (NMO). (C) 2000 Elsevier Science B.V. All rights reserved.
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