Journal
JOURNAL OF CHEMICAL PHYSICS
Volume 112, Issue 11, Pages 4959-4965Publisher
AMER INST PHYSICS
DOI: 10.1063/1.481050
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The reactions of thirteen CmHn+ ions (m less than or equal to 6) with atomic and molecular oxygen and nitric oxide have been measured using a selected ion flow tube operating at room temperature. Rate coefficients and product distributions are reported for each reaction. Most of the hydrocarbon ions studied exhibit relatively rapid reactions with O atoms and proceed at substantial fractions of the collision rate. All O atom reactions showed multiple product channels and the formation of a -C-O bond, either in the ion product or the neutral product of reaction. (C) 2000 American Institute of Physics. [S0021-9606(00)00811-4].
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