☆ 4.5 Article Proceedings Paper

Synthesis of porphyrins: models of natural hemoproteins and impressive catalysts for asymmetric epoxidation of olefins

POLYHEDRON (2000)

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Journal

POLYHEDRON
Volume 19, Issue 5, Pages 581-586

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0277-5387(99)00413-1

Keywords

porphyrins; hemoprotein models; chiral catalysts; epoxidation; olefins

Categories

Chemistry, Inorganic & Nuclear Crystallography

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Porphyrins, with two chiral binaphthyl handles, efficiently catalyze the epoxidation of terminal olefins to give epoxides with high enantiomeric excess and turnover number. (C) 2000 Elsevier Science Ltd All rights reserved.

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