Journal
PHYSICAL REVIEW LETTERS
Volume 84, Issue 12, Pages 2730-2733Publisher
AMERICAN PHYSICAL SOC
DOI: 10.1103/PhysRevLett.84.2730
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Using an iterative solution in Laplace-Fourier space, we supply a rigorous mathematical proof for the long-time asymptotics of reversible binding in one dimension. The asymptotic power law and its concentration dependent prefactor result from diffusional and many-body effects which, unlike for the corresponding irreversible reaction and in classical chemical kinetics, play a dominant rule in shaping the approach to equilibrium.
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