Journal
ORGANIC LETTERS
Volume 2, Issue 6, Pages 807-809Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol005554l
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An alpha-CF3-carbenium ion stabilized by a bimetallic [Co-Co] cluster was prepared and isolated in good yield, starting from the corresponding alcohol by action of HBF4/Et2O. C-N and C-C bonds with nitrogen and carbon nucleopfriles could be easily formed. Subsequent decomplexation gave the free substituted beta-CF3 alkynes in good yields.
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